Physiological Chemistry Lecture

Caren Seagraves
617-287-6133
E-Mail: centercls@gmail.com
Office: S-130
Office hours: Mon. 1-2, Thurs. 10-12 and 1-2.

This page gives resources that relate directly to the lecture. Keep in mind that CHEM 130 has 3 components: Lecture, Lab, and Discussion. You must take each part in order to receive credit for Chem 130. This website only has material that relates to the lecture. Information relating to laboratory can be found here.

***Exam 3 has been moved to April 17!***

 

General Class Information | Powerpoints | Homework & Practice | Keypoints for Exams | Textbook Powerpoints

 

Announcements

Here is the link to the modified Keypoints and Mainpoints lists that should be used to study for the final.  Final Keypoints/Mainpoints 

 

I have prepared a worksheet and answer sheet that will give you an idea of the type of numeric questions that you can expect on the final exam.

 

This is a link to a .pdf file that has the glycolysis diagram that you will be given on the exam.  Please take the time to study it by comparing it with your notes and the textbook.  Test Diagram

 

I have also prepared a page “How to Answer Open Response Questions”, that shows how to answer open response questions.  Please take the time to look at this, and its companion “How Not to Answer Open Response Questions” .

 

This the new class web page.  If you need something from the old page that you can’t find here, here is a link to the old one.  I will no longer update the old page.

 

General Class Information

Course Syllabus

Course Schedule

pdf file of the periodic table

 

Powerpoints from Lecture

These are the powerpoints that will be and have been used in lecture. When you are going over the powerpoints before be sure to make notes of your questions so that you can be sure they are addressed in lecture. I plan on adding new powerpoints over the weekends or on Friday afternoon. In most cases I should have the week's powerpoints up before the week begins. In some cases there will be differences between the powerpoint presentations I have posted before lecture and those that I use in lecture. These powerpoints give a framework for what goes on in lecture but they are not a substitute for attending lecture, most lectures will contain examples that are not in these powerpoints. If you miss class you must get notes from a classmate and go over the material that you missed with them.

 

DATE ADDED

POWERPOINT SLIDES FROM LECTURE

ADDITIONAL ONLINE READING

JAN 26

 

Course Overview

 

JAN 26

Introduction to Chemistry

Google Books Description of Matter Classification
Don't worry about the different types or heterogeneous mixtures.

ChemProfesssor Classification of Matter
This is another description of the classification of matter, it has many examples and is clearly worded.

Identification of Mixtures and Pure Substances Flow Chart

Separation Of Mixtures - From Discussion

 

JAN 30

Numbers and Units

 

Google Video of a lecture on significant figures.
I think this is a very clear lecture and I would like to know what you think.

Factor Product Video
This is a video lecture about factor product method. It is a god resource and I highly recommend it to anyone who is feeling unsure about the mathematics in this course. Factor-Product is also called Dimensional Analysis.

Introduction to the Factor-Product Method
This introduction ends with an example that uses more chemistry than you may know right now, but the method is clear even if the reasons are not.

 

FEB 2

Scientific Notation and Atomic Structure

 

 

FEB 4

Periodic Trends Lecture

 

 

FEB 6

Atomic Structure And Periodic Trends I

 

Intro to Atomic Structure I
First, do not hate me for including a site that is aimed at kids. Just keep this bookmark so that you can use this site with your own children. This site has many very good introductions to topics and I know profs who, wrongly, will copy the text from this site and hand it out to student because they don't want their students to be offended that it is meant for kids. I can't see doing this.

Intro to Atomic Structure II
This site covers all of the material about basic atomic structure that we will consider in this course. (We will return to atomic structure but at a bit more complex level.) You should be able to do the quiz at the end of this reference.

Summary of Atomic Structure
The basics of atomic structure on one sheet.

Atomic Structure Video

 

FEB 9

Atomic Structure And Periodic Trends II

 

Introduction to Atomic Orbitals
This is a reference that covers material in the "Atomic Structure and Periodic Trends" Lecture. Unless you know this stuff very well make the time to read this.

Interactive display gives the occupation of orbital shells and subshells,
You may use this page to teach yourself about how electron orbitals are filled.

Trends of the Periodic Table
This site gives a clear description of periodic trends. It does not relate everything back to the changes seen in atomic radii as we have done in lecture but it is written clearly and reinforces the ideas we went over in lecture. It also includes electronegativity and melting point as part of periodic trends. Electronegativities are similar to electron affinity. Melting point is the temperature at which a solid becomes a liquid."

Periodic Properties of the Elements: Trends in the Periodic Table
This reference describes trends we observed in the periodic table.

 

FEB 9

Radii and Reactivity

 

 

FEB 11

Chemical Formulas and Equations

 

Interpreting Formulas Quiz
This is a short but excellent quiz.

Rules for Balancing Chemical Equations

 

FEB 13

Ions, Noble Gases, Salts, and Covalent Bonds

 

An Interactive Slide Show on Ionic Bonds
This interactive slide show does a good job explaining what ionic compounds are and how they are formed. Its images and wordings are clear and make watching this worthwhile. It does not consider whys other than to say that metals generally lose electrons while nonmetals gain.

Description of Ionic and Covalent Bonds
This is pretty reasonable site describing ionic and covalent bonds. Keep in mind that animations are cartoons. They are meant to illustrate of was of thinking about the bonds but they are not meant to represent what is going on. Just as the chemical symbols with the dots around them are a very nice way to keep count of electrons they do give a picture of what a molecule looks like.

 

FEB 18

Molecular Geometry and Dipole Moments

 

Dot Structure Tutorial

Lewis Dot Structures I
A good Discussion of Lewis Dot structures.

Lewis Dot Structures II
This is a less wordy description of Lewis dot structures. Many of you may find that you prefer the instruction for drawing Lewis Dot structures that is provided at this site

VSEPR I
This site has a pretty reasonable description of the VSEPR Model of predicting molecular geometry. This is the method we have been using but we are only considering a central atom with 3 objects (atoms or lone pairs), or 4 (atoms or lone pairs) around. More are considered here but the description is the same.

VSEPR II
This is a description of VSEPR that is short on words but still has enough information.

 

FEB 23

Moles and Concentrations

 

What is a mole?
Discusses Moles as a unit of measure, and explains why having this unit is useful. Note that when she describes a mole as a unit of measure, it is different from what I presented in lecture. In lecture I presented a mole as a counting unit, like a dozen, or a gross.

Calculating Molar Masses
Clear instructions on how to calculate molar masses of molecules. There is a mistake in this write up though, when they gave the molecular mass of water at the end they used an "8" when they should have used an "18".

Calculating Amounts of Reactants and Products
This is a video that describes the sort of calculation that we did in lecture on Monday 2/23. The video is clear, and it is useful, in part because it combines the 3 steps that we did in class into 1 step and many of you may prefer this method, to using separate steps.

 

FEB 25

Solutions and Concentrations

 

Introduction to Molarity
An introduction to Molarity with example problems

Description of Concentrations by Percents, ppm, and ppb. This is a brief description of concentration by percents, ppm and ppb. There are several worked example problems.

 

FEB

Dilutions

 

 

FEB 27

Background for Protein Chemistry

Bond and Molecular Polarity
This site discusses charge separation in ionic and covalent bonds. It has simple animations and can take a few seconds to load. Don't assume it is a broken link until your browser says so.

Intermolecular Forces
This site discusses the forces that hold molecules together as solids and liquid, electrostatic forces, dipole-dipole forces, hydrogen bonding, and London Forces.

 

March 4

Acids and Bases

Acids and Bases
This is a clear description of acids and bases.

Conjugate Acid Base Pairs

The Nature of Bases

Read up to “Explaining Differences in Base Strengths.

March 23

Thermodynamics

Chapter 7, without the section on equilibrium constants and LeChatelier’s Principle

March 27

Amino Acids and Proteins

Chapter 18 sections 18.1-18.8

March 30

Amino Acids and Proteins Pt.2

Chapter 18, all sections

April 1

Enzymes

Chapter 19, up to the section on vitamins

April 3

Vitamins

Chapter 19, complete chapter

April 6 and April 9

Generation of Biochemical Energy

Chapter 21, complete chapter

April 9

Carbohydrates

Chapter 22 Reading Assignment

April 20

Carbohydrate Metabolism

No Powerpoints

Carbohydrate Metabolism Mainpoints

Chapter 23 Complete Chapter

Glycolysis Animation

Extra and Advanced Reading on Glucose Metabolism (This is only if you are interested and you have the time to read this.  It does not reflect what you need to know in this class.)

April 23

Lipids

Introduction to Lipids Mainpoints

Chapter 24 Complete Chapter

May 6

Lipids Digestion and Transportation

Lipids Digestion and Transportation Mainpoints

Chapter 25, through 25.2, including the Application “Lipids and Atherosclerosis”

 

Homework Assignments

These are grouped according to the content not the dates of the assignment. The assignment titles match what is on the powerpoint titles, but the powerpoints do not necessarily contain all of the information that you will need to do the assignments. You will need to check with other resources, the text, other handouts, lecture notes, and/or come to office hours or make an appointment. Do not let yourself fall behind, or decide that you can put off understanding the ones that seem hard until the exam.

The answer to many of the homework problems are posted across from my office, which is room 130, floor 1 of the science building. There are example answers to almost every type of problem you will see, use these answers to develop strategies for the problems that don't have answers. If you can't figure a problem out after trying for 20  minutes get help from me or a friend.

Date Posted

Written Homework Assignments

Additional Online Practice

 

Mixtures and Pure Substances

 

Classification of Matter Summary and Practice Problems

 

 

Measurements and Significant figures

 

An interactive problem set that lets you practice recognizing the number of significant figures in a number.

An Excellent Significant Figure Online Quiz Generator
It has very clear explainations of the answers. You finish a whole page of problems before checking your answers, though.

Rounding Practice I
A rounding that is very basic, but it would be a good place to start if you have not rounded numbers for a while. It only practice rounding, it does not teach the whys at all.

Rounding Practice II
This is excellent rounding practice and at the level required for this class. In these you consider significant figures as well as rounding.

 

 

Scientific Notation and Unit Conversions

 

Unit Conversion Practice I
When calculating the volumes, convert the units for each side before calculating the volume. Problems 5, 8, 7,9 have the wrong number of Significant Figures

Unit Conversion Practice II
Use a table to identify the SI prefixes and their relative sizes.

Unit Conversion Practice III
In the question when they ask about 430 mmHg they cannot be sure that there are 2 significant figures. Do not worry about the question about specific gravity

 

 

Basic Atomic Structure and the Periodic Table

 

 

 

Electron Configuration Homework
This assignment is from a website, but print it out and do it as a written homework assignment. Though I did not write if it reflects what you are expected to know. You will not be able to access the answer but a key will be availale on the bulletin board.

 

Atomic Orbital Diagram Practice
Place electrons in atomic orbital diagrams. The script gives an immediate response with hints to solve the problem. You will need a periodic table to do these problems.

Principles of Quantum Mechanic Quiz
Select the quiz "Atomic Theory III: The Quantum Mechanical Model."

Electron Configuration Quiz
Select the quiz "Electron Configurations." There are many other quizzes on this subject but this is the only one that relates to material in this course.

 

 

Atomic Radii and Periodic Trends
This is a quiz that I reformated and edited to reflect what we have done in class. This problem set is from the chemcool website

 

 

 

Names and Formulas of Ionic Compounds

Answer Key

 

 

 

 

Balancing Equations Practice
This assignment is from a website, but print it out and do it as a written homework assignment. Though I did not write if it reflects what you are expected to know. The answer key for these problems is in the same .pdf file.

 

Chembalancer I
This is a good balancing equation practice. On my browser the page looks a bit odd but all of the information is there. Once you have filled the boxes in with the coefficients you pressed the "Balanced" button in the green box to check your answer.

Chembalancer II
This is a chance for balancing chemical equations it is a step harder than chembalancer I

Balancing Practice with Hints
This online practice site has hints to help if you get stuck balancing problems. This is a nice feature plus it lets you chose how many problems you want to do before checking your answers.

 

 

Lewis Dot Structure Problem Set

There is a written tutorial in the Reference section that supports this problem set.

 

Lewis Dot Structure VESPER Practice
Practice drawing Lewis dot structures and identifying objects around the central atom.

Online VSEPR and Intermolecular Forces Quiz
This is a pretty good online VSEPR Quiz. I have only done the Level 1. If your computer does not show the formulas just enter the molecules name in google, and it will be easy to find out what the formula is. There is a chance to answer 3 questions about each molecule. Its geomentry, by which they mean the shape of the molecule when all of the objects around it are considered. The shape of the molecule, by which they mean the shape formed when only atoms are considered. Finally when C is selected the quiz asks about the kind of forces that may act between molecules of this type. This is something that we will get to on Monday Feb. 23.

 

 

Reactants & Products

Calculating Amounts of Reactants and Products I
This is a short problem set that follows a video on this subject. I highly recommend doing this quiz.

Calculating Amounts of Reactants and Products II
Here is a quiz that provides a chance to practice using the number of moles of either products and a balanced chemical equation to determine the amount of another element or compound that is part of the equation. These questions are at the level that we did in class and in Discussion section. In the instructions for this quiz it indicates that calculators should not be used. This prejudice against calculators belongs to the person who made this quiz, not me. Use a calculator.

Calculating Amounts of Reactants and Products III
This is an online quiz that covers what we did in class on 2/23, but in a way that requires a good understanding of the concepts involved. Do this quiz after you feel comfortable with calculating molecular molar masses. The last question is about limiting reagents. We will not be covering limiting regents in depth so just skip this one.

 

 

Molarity Calculations

Go to Calculate Molarity - Interesting Substances. This is a 3 problem online quiz. Unlike the quizzes that are below and meant for practice these problems are homework problems and a key for them will be posted across from my office. This program generates more than 3 questions if you return to it repeatedly. If you get it after 3 questions you are done otherwise try a few more.

Answer Key

 

Molarity I
A quiz in which you do basic calculations relating, # of moles, volume and molarity.

Molarity II
A quiz composed of molarity word problems. In some of these problems you need to bring what we did in lecture on 2/23 together with molarity problems You will need to do problems at this level for this class.
#5 answer key

 

 

 

Percents, ppm and ppb Problem Set
These are homework problems that are typical calculations. The numeric answers are given at the end of this problem set.

 

Concentration Calculations Practice
These are fairly straight forward concentration calculations. The numeric answers to these problems are given on the last page of this handout.

 

 

Acids & Bases Homework1

Acids & Bases Homework1 Answer Key

-----------------------------------

Acids & Bases Homework 2

(Multiple Choice Answer Key)

Multiple Choice Acid Base Review Quiz
Use these questions to help you review lecture and to direct you to what subjects you need to review.

Multiple Choice Acid Base Review Quiz II
Use these questions to help you review lecture and to direct you to what subjects you need to review. Ignore # 14. It does not make sense.

ThermodynamicsReview

April 3

Proteins

April 6

Enzyme Book Problems

April 10

Generation of Biochemical Energy Homework and Reveiw

 

April 10

Carbohydrates Book Problems

 

April 20

Cabohydrate Metabolism Book Problems

 

April 23

Lipids Book Problems

 

Keypoints & Answer Keys for Exams & Quizzes

Quiz/Exam #

Keypoints

Answer Keys

Quiz 1

Exam 1

Keypoints Classification of Matter

Keypoints Units and Numbers

Keypoints Basic Atomic Structure

Keypoints Periodic Table Groups and Reactivities

Atomic Orbitals and Periodic Trends

Keypoints Chemical Formulas and Equations

Keypoints Noble Gas Configurations, Ions, and Covalent Bonds

This handout links the questions in Exam 1 to the corresponding Keypoints. It is not really an answer key but this seemed to be the best place for it.

Quiz 2

Quiz 2 Answer Key

Exam 2

Keypoints on Lewis Dot Structures and VSEPR

Keypoints Stoichiometry

KeypointsProblems

Partial Problem Key

Exam 2 Answer Key
This answer key gives the answers for all of the questions and links to resources available through this website that will help you understand the material, and get the practice that you need in order to solve the problems on the Exam. I have given detailed examples of how to solve the longer problems on the exam. The links offer many chances to solving similar problems. Practicing how to do these problems is the key to being able to recognize them and solve them readily, which is what you need to be able to do on an exam.

Quiz 3

Quiz Announcement Sheet

Quiz 3 Answer Key

Exam 3

Keypoints

Amino Acids and Proteins

Enzymes and Vitamins

Generation of Biochemical Energy

Carbohydrates

 

 

 

Final

Keypoints/Mainpoints

 

 


Textbook Powerpoints

These are links to powerpoint slides for the text Fundamentals of General, Organic, and Biological Chemistry. Most of the information has not been covered in lecture because the text is meant for a yearlong course. This can lead to confusion, which is why the first part of the text has not traditionally been the required text for this course. If you use these powerpoints to study use the Keypoint lists to focus on the topics that are covered in this course. You will still need the powerpoints that I have prepared as well as the websites that I have given links to.

Chapter 1

Chapter 2

Chapter 3

Chapter 4

Chapter 5

Chapter 6

Chapter 7

Chapter 8

Chapter 9

Chapter 10